Preparation and Polymerization of Vinyl Bicyclo (2, 2, 1)-heptane-2-carboxylate
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چکیده
منابع مشابه
PREPARATION AND MOLECULAR STRUCTURE OF 2-BENZYLAMINOPYRIDINE COPPER(1) COMPLEX
2-Benzylaminopyridine (HBAP) reacts with NaH in THF and generates the sodium salt (NaBAP). Further reaction of [Cu(TMEDA) ] [CuCl ] with one equivalent of this ligand in THF leads to the formation of a dimeric Cu(1) complex, [Cu (BAP)] . H 0. The molecular structure has been determined by using a single-crystal X-ray diffraction method. The yellow compound crystallizes in the monoclinic s...
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epoxyalcohols are useful intermediates in complex organic synthesis, and recently they have been recognized as versatile intermediates for synthesis of natural products. the treatments of cis and trans 2-(1-cyclohexenyl) cyclohexanol, separately with paranirto perbenzoic acid gave the corresponding 2-(1- cyclohexenyl) cyclohexanol oxide. on the other hand, 2-cyclohexylidene cyclohexanol oxide w...
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The acetone sensitized photolysis of the title compound gave 2-(2- oxopropy1)-9,9- dimethyl bicyclo [3.3.l]nona-3-one. A bridgehead cyclopropane intermediate was then suggested for the formation of the photoproduct
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In the title compound, C(9)H(14)BNO(4), the carbonyl and boronic acid groups are essentially coplanar with the pyrrole ring and the boronic acid group has an exo-endo conformation. The exo-oriented OH is engaged in an intra-molecular O-H⋯O inter-action, while the endo-oriented one is involved in inter-molecular hydrogen bonding to form centrosymmetric dimers. A supra-molecular assembly is achie...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1963
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.66.6_832